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71.
Henrik Peisker Lars Heepe Alexander E. Kovalev Stanislav N. Gorb 《Journal of the Royal Society Interface》2014,11(99)
Wet adhesive systems of insects strongly rely for their function on the formation of capillary bridges with the substrate. Studies on the chemical composition and evaporation dynamics of tarsal secretions strongly suggest a difference in chemistry of secretion in beetles and flies, both possessing hairy attachment devices. This difference is assumed to influence the viscosity of the secretion. Here, we applied a microrheological technique, based on the immersion of nanometric beads in the collected tarsal footprints, to estimate secretion viscosity in a beetle (Coccinella septempunctata) and a fly (Calliphora vicina). Both species studied possess distinct differences in viscosity, the median of which was calculated as 21.8 and 10.9 mPa s, respectively. We further present an approximate theoretical model to calculate the contact formation time of spatula-like terminal contact elements using the viscosity data of the covering fluid. The estimated contact formation time is proportional to the tarsal secretion viscosity and to the square of the contact radius of the contact element. 相似文献
72.
Laura E. Turner Henrik Kragh Sørensen 《Centaurus; international magazine of the history of science and medicine》2013,55(4):385-411
As a reaction to the changed political landscape in Scandinavia following the dissolution of the union between Norway and Sweden in 1905, the prominent Swedish mathematician Gösta Mittag‐Leffler extended ‘a brotherly hand,’ calling for Scandinavian colleagues to meet for a congress of mathematicians in Stockholm in 1909. This event became the first in a series of biannual meetings which proved to be an important institution for Scandinavian mathematics. During the first decades after 1909, the congresses would form and consolidate themselves through the construction of a new Scandinavian identity for mathematicians which developed alongside and in relation to both international and national contexts and developments. In this paper, we shall demonstrate that these meetings served a complex set of agendas at the individual, national, and international level. In particular, they reflect a changing conception of cooperation in science for mutual cultural gain combined with a flexible institutionalisation that allowed the Scandinavian mathematicians to use the congresses for various diplomatic ambitions. We base our analyses of the Scandinavian Congresses of Mathematics on the notion of a shared ‘conational’ identity developed adjacent to national identities. We then analyse the formation, consolidation, delineation, and reflections of this institution in order to demonstrate how the efforts to unite Scandinavian mathematicians were contingent on and influenced by simultaneous currents of internationalisation and shared history, culture, and language in the Scandinavian region. 相似文献
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The load capacity of bonded joints can be increased if transverse pressure is applied at the interface. The transverse pressure is assumed to introduce a Coulomb-friction contribution to the cohesive law for the interface. Response and load capacity for a bonded single-lap joint was derived using non-linear fracture mechanics. The results indicated a good correlation between theory and tests. Furthermore, the model is suggested as theoretical base for determining load capacity of bonded anchorages with transverse pressure, in externally reinforced concrete structures. 相似文献
77.
Christian Sandström Henrik Berglund Mats Magnusson 《Creativity & Innovation Management》2014,23(4):472-483
The literature on disruptive innovation has convincingly explained why many established firms encounter problems under conditions of discontinuous change. Incumbents fail to invest in new technologies that are not demanded by their existing customers. This argument is grounded in resource dependency theory and the associated assumption that existing customers control a firm's internal resource allocation processes. While the problem of disruptive innovation has been convincingly explained, there is still a need for managerial solutions. We argue that a key reason why such solutions are lacking can be found in the asymmetric assumptions made in the original theory of disruptive innovation. Specifically, we identify two related forms of asymmetry. First, the focal (incumbent) firm is treated as a collection of heterogeneous actors with different preferences, incentives and competencies, whereas firms in the surrounding environment are treated as if they contained no such heterogeneity. Second, the theory of disruptive innovation describes incumbents as controlled by their environment, but has failed to recognize that the environment can also be influenced. In this paper we argue that a more symmetric theory of disruptive innovation – i.e. one that treats all similar entities in the same way – opens up for a range of interesting managerial solutions. 相似文献
78.
Combination of Reaction and Separation in Heterogeneous Catalytic Hydrogenation of Ethylformate 下载免费PDF全文
Gerson Martin Carla Pereira Frank Pettersson Henrik Saxén Dmitry Y. Murzin Alírio Rodrigues Tapio Salmi 《化学工程与技术》2015,38(5):804-812
Continuous hydrogenation reaction of ethyl benzoylformate was studied over a (–)‐cinchonidine (CD)‐modified Pt/Al2O3 catalyst. The catalyst showed a good stability, and high enantioselectivity was achieved in the fixed‐bed reactor. Chromatographic separation of (R)‐ and (S)‐ethyl mandelate originating from a post‐continuous hydrogenation reaction of ethyl benzoylformate over the (–)‐CD‐modified Pt/Al2O3 catalyst was investigated in the same reaction mixture. A commercial column filled with a chiral selector resin was chosen as a perspective preparative‐scale adsorbent. Since adsorption equilibrium isotherms were linear within the entire investigated range of concentrations, they were determined by pulse experiments for the isomers present in a post‐reaction mixture. Breakthrough curves were measured and described successfully by the dispersive plug‐flow model with linear driving force approximation. 相似文献
79.
Dr. Sean Lund Taylor Courtney Dr. Gavin J. Williams 《Chembiochem : a European journal of chemical biology》2019,20(17):2217-2221
Isoprenoids are a large class of natural products with wide-ranging applications. Synthetic biology approaches to the manufacture of isoprenoids and their new-to-nature derivatives are limited due to the provision in nature of just two hemiterpene building blocks for isoprenoid biosynthesis. To address this limitation, artificial chemo-enzymatic pathways such as the alcohol-dependent hemiterpene (ADH) pathway serve to leverage consecutive kinases to convert exogenous alcohols into pyrophosphates that could be coupled to downstream isoprenoid biosynthesis. To be successful, each kinase in this pathway should be permissive of a broad range of substrates. For the first time, we have probed the promiscuity of the second enzyme in the ADH pathway—isopentenyl phosphate kinase from Thermoplasma acidophilum—towards a broad range of acceptor monophosphates. Subsequently, we evaluate the suitability of this enzyme to provide unnatural pyrophosphates and provide a critical first step in characterizing the rate-limiting steps in the artificial ADH pathway. 相似文献
80.
Johan M. Ahlstrm Alberto Alamia Anton Larsson Claes Breitholtz Simon Harvey Henrik Thunman 《国际能源研究杂志》2019,43(3):1171-1190
The demand for biofuels and biochemicals is expected to increase in the future, which will in turn increase the demand for biomass feedstock. Large gasification plants fueled with biomass feedstock are likely to be a key enabling technology in a resource‐efficient, bio‐based economy. Furthermore, the costs for producing biofuels and biochemicals in such plants could potentially be decreased by utilizing inexpensive low‐grade residual biomass as feedstock. This study investigates the usage of shredded tree bark as a feedstock for the production of biomethane in the GoBiGas demonstration plant in Gothenburg, Sweden, based on a 32 MWth industrial dual fluidized bed gasification unit. The plant was operated with bark feedstock for 12 000 hours during the period 2014 to 2018. Data from the measurement campaign were processed using a stochastic approach to establish the plant's mass and energy balances, which were then compared with operation of the plant with wood pellets. For this comparison, an extrapolation algorithm was developed to predict plant performance using bark dried to the same moisture content as wood pellets, ie, 8%w.b. Plant operation with bark feedstock was evaluated for operability, efficiency, and feedstock‐related cost. The gas quality achieved during the test period was similar to that obtained for operation with wood pellets. Furthermore, no significant ash sintering or agglomeration problems were observed more than 750 hours of operation. The calculated biomass‐to‐biomethane efficiency is 43% to 47% (lower heating value basis) for operation with wet bark. However, the predicted biomass‐to‐biomethane efficiency can be increased to 55%–65% for operation with bark feedstock dried to 8% moisture content, with corresponding feedstock costs in the range of 24.2 to 32.7 EUR/MWh; ie, a cost reduction of about 40% compared with wood pellets. 相似文献